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FUELS FROM TAR SAND BITUMEN
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Tar sand bitumen is another source of liquid fuels that is distinctly separate from conventional petroleum (US Congress, 1976; Speight, 2005, 2007) Tar sand (also called oil sand in Canada) or the more geologically correct term bituminous sand is commonly used to describe a sandstone reservoir that is impregnated with a heavy, viscous bituminous material Tar sand is actually a mixture of sand, water, and bitumen but many of the tar sand deposits in countries other than Canada lack the water layer that is believed to facilitate the hot water recovery process The heavy bituminous material has a high viscosity under reservoir conditions and cannot be retrieved through a well by conventional production techniques Geologically, the term tar sand is commonly used to describe a sandstone reservoir that is impregnated with bitumen, a naturally occurring material that is solid or near solid and is substantially immobile under reservoir conditions The bitumen cannot be retrieved through a well by conventional production techniques, including currently used enhanced recovery techniques In fact, tar sand is defined (FE-76-4) in the United States as:
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The several rock types that contain an extremely viscous hydrocarbon which is not recoverable in its natural state by conventional oil well production methods including currently used enhanced recovery techniques The hydrocarbon-bearing rocks are variously known as bitumen-rocks oil, impregnated rocks, tar sands, and rock asphalt
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In addition to this definition, there are several tests that must be carried out to determine whether or not, in the first instance, a resource is a tar sand deposit (Speight, 2007 and references cited therein) Most of all, a core taken from a tar sand deposit, the bitumen isolated therefrom, are certainly not identifiable by the preliminary inspections (sight and touch) alone In the United States, the final determinant is whether or not the material contained therein can be recovered by primary, secondary, or tertiary (enhanced) recovery methods (US Congress, 1976) The relevant position of tar sand bitumen in nature is best illustrated by comparing its position relevant to petroleum and heavy oil Thus, petroleum is referred to generically as a fossil energy resource and is further classified as a hydrocarbon resource and, for illustrative (or comparative) purposes in this report, coal and oil shale kerogen have also been included in this classification However, the inclusion of coal and oil shale under the broad classification of hydrocarbon resources has required (incorrectly) that the term hydrocarbon be expanded to include these resources It is essential to recognize that resources such as coal, oil shale kerogen, and tar sand bitumen contain large proportions of heteroatomic species Heteroatomic species are those organic constituents that contain atoms other than carbon and hydrogen, for example, nitrogen, oxygen, sulfur, and metals (nickel and vanadium)
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Copyright 2008 by The McGraw-Hill Companies, Inc Click here for terms of use
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CHAPTER FOUR
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Use of the term organic sediments is more correct and is preferred The inclusion of coal and oil shale kerogen in the category of hydrocarbon resources is due to the fact that these two natural resources will produce hydrocarbons by thermal decomposition (high-temperature processing) Therefore, if either coal and/or oil shale kerogen is to be included in the term hydrocarbon resources, it is more appropriate that they be classed as hydrocarbon-producing resources under the general classification of organic sediments Thus, tar sand bitumen stands apart from petroleum and heavy oil not only from the method of recovery but also from the means by which hydrocarbons are produced It is incorrect to refer to tar sand bitumen as tar or pitch In many parts of the world the term bitumen is used as the name for road asphalt Although the word tar is somewhat descriptive of the black bituminous material, it is best to avoid its use with respect to natural materials More correctly, the name tar is usually applied to the heavy product remaining after the destructive distillation of coal or other organic matter Pitch is the distillation residue of the various types of tar Physical methods of fractionation of tar sand bitumen can also produce the four generic fractions: saturates, aromatics, resins, and asphaltenes However, for tar sand bitumen, the fractionation produces shows that bitumen contains high proportions of asphaltenes and resins, even in amounts up to 50 percent w/w (or higher) of the bitumen with much lower proportions of saturates and aromatics than petroleum or heavy oil In addition, the presence of ash-forming metallic constituents, including such organometallic compounds as those of vanadium and nickel, is also a distinguishing feature of bitumen
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