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Natural Cycles and Energy Flow 119
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Table 101 Atmosphere
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Carbon is stored in various areas above and below the earth
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QUANTITY (BILLIONS OF METRIC TONS)
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CARBON STORAGE
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580 (1,700) 800 (2,000) 1,500 1,600 38,000 40,000 66,000,000 100,000,000 540 610 4,000
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Organic (soil) Ocean Ocean sediments and sedimentary rocks Land plants Fossil fuels
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Geologists are interested in carbon because it is such a versatile element Not only does carbon exist in the air, land, and sea but humans are made up of approximately 50% carbon by dry weight Environmental chemists study different ecosystems with carbon balancing accounts using crop productivity, food chains, and nutrient cycling measurements
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KEY IDEA
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The carbon cycle involves the Earth s atmosphere, fossil fuels, oceans, soil, plants, and animal life of terrestrial ecosystems
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In addition, carbon dioxide is the main atmospheric greenhouse gas thought to be a result of human activities Until alternative power sources, like solar power, are developed and used more, atmospheric carbon dioxide increases will result mostly from burning fossil fuels Geologists look for patterns when trying to understand seasonal carbon drops and gains in atmospheric carbon dioxide We ve seen how global photosynthesis and respiration have to be equal or carbon will either accumulate on land or be released to the atmosphere Measuring year-to-year changes in carbon storage is tough Some years have more volcanic eruptions with extra carbon in the air, while other years or decades have less However, some measurements are clear The clearing of forests for crops is well documented, both historically and from satellite data When forests get a chance to grow back on cleared land, they pull carbon from the atmosphere and start saving it up again in trees and soils The change between total carbon released to the atmosphere and the total pulled back down governs whether the land is a supplier or reservoir of atmospheric carbon Atmospheric carbon = fossil fuels + land use changes ocean uptake unknown carbon deposit
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When considering the global carbon equation between the atmosphere, fossil fuels, and the oceans, the global carbon tally is not completely known Research is ongoing to discover the location of unknown carbon reservoirs
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Calcium
Calcium makes up roughly 34% of the Earth s crust and has been around since the formation of the Earth It is found in igneous rocks as calcium silicates, and in sedimentary and metamorphic rocks as calcium carbonates When rock weathering takes place by acid rain or plant growth and decay, calcium interacts with water and is transported to another location Water helps calcium move from the land to the oceans High concentrations of dissolved calcium and/or magnesium in fresh water cause hard water When these minerals are concentrated in water, around 89 to 100 parts per million, they don t react well with soap In fact, mineral rings form in bathtubs, and laundered clothes take on a gray color from undissolved soap scum Undissolved minerals in hard water are also deposited in plumbing, coffee pots, and steam irons Frequently, people living in hard water areas use water softeners chemicals that remove calcium and magnesium ions in an exchange with sodium ions Hard water can have benefits In the aquatic environment, calcium and magnesium help keep fish from absorbing metals like lead, arsenic, and cadmium into the bloodstream through their gills Therefore, the harder the water, the less potential for toxic metals to be absorbed by fish In seawater, calcium concentrations are 100 to 1,000 times higher than land levels, and even greater concentrations are found in deeper, colder waters with little circulation Calcium can reside roughly a million years in the ocean before it appears on land again Calcium ions stay in ocean water until they are precipitated out as calcium carbonate Although upper ocean levels are highly saturated with calcium and carbonate ions, saturation depends on location and conditions Photosynthesis and temperature affect warm, shallow water, lowering levels of carbon dioxide These conditions allow calcium carbonate to precipitate either inorganically or through aquatic organisms When calcium carbonate is used by marine inhabitants to build shells, it is called biomineralization As these organisms die, their hard shells sift down to the ocean s floor and gather or dissolve depending on depth, temperature, and pressure Shells sinking to the deepest parts of the ocean often redissolve because of higher carbon dioxide levels in the colder, deeper waters The dividing line separating an area where calcium carbonate dissolves and accumulates is called the lysocline The calcium carbonate deposited by microorganisms is often mixed with other ocean sediments or washed from the land depending on location Birds, animals, and humans eat seafood and shellfish, discarding the shells This returns calcium back to the Earth fairly rapidly However, most calcium is transported by plate tectonics Crustal plates and continental land masses with their mountain-building movement help calcium carbonate deposits move toward the surface in the form of limestone or marble (if changed by pressure and temperature) Figure 103 illustrates the different compounds of the calcium cycle
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