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U Answers and Explanations
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a 2C6H14 + 19O2 12CO2 + 14H2O Give yourself 2 points for the answer shown above, or for the coefficients: 1, 9/2, 6, and 7 Give yourself 1 point if you have one or more, not all, of the elements balanced
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3 b ( 487 kJ/100 g hexane) (8617 g hexane/mol hexane) = 420 10 kJ/mol
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Give yourself 2 points for the above setup and correct answer (this requires a negative sign in the answer) If the setup is partially correct, give yourself 1 point c The ideal gas equation should be rearranged to the form P = nRT /V n = (500 g hexane) (1 mol hexane/8617 g hexane) (12 mol CO2/2 mol hexane) = 03481 mol CO2 This answer has an extra significant figure The mole ratio should match the one given in your balanced equation You will not be penalized again for an incorrectly balanced equation You will lose a point if you do not include a hexane-to-CO2 conversion R = 00821 L atm/mol K This value is given in your test booklet T = 27 + 273 = 300 K You will be penalized if your forget to use the Kelvin temperature V = 200 L P = (03481 mol CO2) (00821 L atm/mol K) (300 K)/(200 L)= 0429 atm Give yourself 2 points for the correct setup and answer Give yourself 1 point if you did everything correctly, except the mole ratio or the Kelvin conversion
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Organic Chemistry 277
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d This part requires Graham s law: r1/r2 = (M2/M1)1/2 If we let 1 refer to hexane, and 2 refer to the unknown vapor, then: r1 = (1/2)r 2, and M1 = 8617 g/mol When these values are entered into the equation:
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(1 2)r
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= M 2 /86 17 g/mol
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Canceling and then squaring both sides gives: (1/2)2 = (1/4) = M2/8617 g/mol M2 = (1/4)(8617 g/mol) = 2154 g/mol Give yourself 2 points for the correct setup and the correct answer It is not necessary to show all the intermediate steps Give yourself 1 point if you make a mistake e You may need to redraw one or more of your answers to match the answers shown below Give yourself 1 point for each correct answer, with a 2-point maximum There are no bonus points for additional answers
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H H H C H C H C H H C C H H H H H H C C H H C H H C C H H H C H H H H C C C C H H H C H C H H C H C H H C H H
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These compounds are 2-methylpentane, 3-methylpentane, 2,2-dimethylbutane and 2,3-dimethylbutane, respectively These four, along with the original n-hexane, are the only isomers If you think you have another isomer, you have simply redrawn one of these Try naming your answer and see if it matches one of these names Total your points The maximum is 10 points Subtract one point if all your answers do not have the correct number of significant figures
U Rapid Review
Organic chemistry is the chemistry of carbon and its compounds Hydrocarbons are organic compounds of just carbon and hydrogen atoms Alkanes are hydrocarbons in which there are only single bonds Alkanes are named in a very systematic way Review the rules for naming alkanes Isomers are compounds that have the same molecular formulas but different structural formulas Review the writing of the various structural isomers of alkanes Make sure that each carbon atom has four bonds A functional group is a group of atoms that is the reactive part of the molecule Review the general functional groups Macromolecules are large molecules that may have molecular masses in the millions Macromolecules are generally composed of repeating units called monomers
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