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Oxidation numbers are bookkeeping numbers that allow chemists to do things like balance redox equations Don t confuse oxidation numbers with the charge on an ion Oxidation numbers are assigned to elements in their natural state or in compounds using the following rules:
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The oxidation number of an element in its elemental form (ie, H2, Au, Ag, N2) is zero The oxidation number of a monoatomic ion is equal to the charge on the ion The oxi2+ dation number of Mg is +2 Note that the charge is written with number first, then sign; for oxidation numbers it is sign, then number The sum of all the oxidation numbers of all the elements in a neutral molecule is zero The sum of all the oxidation numbers in a polyatomic ion is equal to the charge on the ion The alkali metal ions have an oxidation number of +1 in all their compounds The alkaline earth metals have an oxidation number of +2 in all their compounds The oxidation number of hydrogen in compounds is +1, except it is 1 when combined with metals or boron in binary compounds The oxidation number of halogens in their compounds is 1 except when combined with another halogen above them on the periodic table, or with oxygen The oxidation number of oxygen is 2 in compounds, except for peroxides, in which it is 1
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Determine the oxidation number of sulfur in sulfuric acid, H2SO4 The sum of all the oxidation numbers must equal zero, since this is a neutral compound The oxidation numbers of hydrogen (+1) and oxygen ( 2) are known, so the oxidation number of sulfur can be determined: 2(+1) + + 4( 2) = 0 H 2 SO 4 The oxidation number of sulfur in this compound must be +6
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Nomenclature Overview
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This overview covers some of the rules for naming simple inorganic compounds There are additional rules, and some exceptions to these rules The first part of this overview discusses the rules for deriving a name from a chemical formula In many cases, the formula may be determined from the name by reversing this process The second part examines situations in which additional information is needed to generate a formula from the name of a compound The transition metals present some additional problems; therefore, there is a section covering transition metal nomenclature and coordination compounds
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Binary compounds are compounds that consist of only two elements Some binary compounds have special names, and these special names supersede any of the rules given below H2O is water, NH3 is ammonia, and CH4 is methane All other binary compounds have a name with a suffix ide Binary compounds may be subdivided into metal type, nonmetal type, and acid type (a) Metal type These binary compounds begin with metals The metal is given first in the formula In general, metals are the elements on the left-hand side of the periodic table, and the nonmetals are on the right-hand side Hydrogen, a nonmetal, is an exception to this generalization First name the metal, then name the nonmetal with the suffix ide Examples: Formula Na2O MgCl2 Name sodium oxide magnesium chloride
+ The ammonium ion (NH4 ) is often treated as a metal, and its compounds are named under this rule Thus, NH4Cl is named ammonium chloride
(b) Nonmetal type These binary compounds have formulas that begin with a nonmetal Prefixes are used to indicate the number of each atom present No prefixes are used for hydrogen Naming the compounds can best be explained using the following examples: Formula CO SO3 P4O10 Name carbon monoxide sulfur trioxide tetraphosphorus decoxide
Carbon monoxide is one of the very few cases where the prefix mono is used In general, you should not use mono in any other compound Some of the prefixes used to denote the numbers of atoms in a compound are listed below: Number of atoms 1 2 3 4 5 6 7 8 9 10 Prefix mono di tri tetra penta hexa hepta octa nona deca
On many occasions the terminal a or o is dropped for oxides, so they read as pentoxide, heptoxide, or monoxide In normal nomenclature, the nonmetal prefixes are not used if a metal is present One of the few exceptions to this is MnO2, sometimes called manganese dioxide (c) Acid type These binary compounds have formulas that begin with hydrogen If the compound is not in solution, the naming is similar to that of the metal type
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