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66 U STEP 4 Review the Knowledge You Need to Score High
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The IA family is known as the alkali metals; the IIAs are the alkaline earth metals; the VIIAs are the halogens; and the VIIIAs are the noble gases Know why atoms get larger as we go from top to bottom in a group and slightly smaller as we move from left to right on the periodic table Ionization energy is the energy it takes to remove an electron from a gaseous atom or ion It decreases from top to bottom and increases from left to right on the periodic table Much the same trend is noted for electron affinity, the energy change that takes place when an electron is added to a gaseous atom or ion The trends depend on the size of the atom or ion and its effective nuclear charge Oxidation numbers are bookkeeping numbers Know the rules for assigning oxidation numbers Be able to name binary metal type and nonmetal type compounds, as well as ternary compounds, oxyacids, simple coordination compounds, etc
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CHAPTER
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Reactions and Periodicity
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Reactions will always occur in the free-response section of the AP Exam
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AP Exam Format
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Beginning with the 2007 AP exam, the treatment of chemical reactions was changed from previous years In the past, the free-response questions concerning chemical reactions have simply involved the formulas of the reactants and products chosen from a series of reactions You were not expected to write balanced chemical equations However, under the current AP Chemistry exam format you no longer will be able to choose from a list of reactions You will be expected to write a balanced chemical equation for every reaction given and answer one or more questions about each reaction If the reaction occurs in aqueous solution, you will have to write the net ionic equation for the process For the reactions question of the AP exam, you will be expected not only to balance the equation, but to have an understanding of why the reaction occurs The reactions and concepts described may also appear in other parts of the AP exam, such as the multiple-choice sections Again, you will need to have an understanding of why a particular reaction occurs As you study this chapter, pay particular attention to the explanations that accompany the reactions and equations You will be expected to demonstrate your understanding on the AP exam
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IN THIS CHAPTER Summary: Chemistry is the world of chemical reactions Chemical reactions power our society, our environment, and our bodies Some chemical species called reactants get converted into different substances called products During this process there are energy changes that take place It takes energy to break old bonds Energy is released when new bonds are formed Does it take more energy to break the bonds than is released in the formation of the new bonds If so, energy will have to be constantly supplied to convert the reactants into products This type of reaction is said to be endothermic, 67
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68 U STEP 4 Review the Knowledge You Need to Score High
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absorbing energy If more energy is released than is needed to break the old bonds, then the reaction is said to be exothermic, releasing energy The chemical reactions that provide the energy for our world are exothermic reactions In 9 Thermodynamics, you can read in more depth about the energy changes that occur during reactions Reactions occur because of collisions One chemical species collides with another at the right place, transfers enough energy, and a chemical reaction occurs Such reactions can be very fast or very slow In the chapter on Kinetics, you can study how reactions occur and the factors that affect the speed of reactions But in this chapter we will review the balancing of chemical equations, discuss the general types of chemical reactions, and describe why these reactions occur
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