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Elements on this activity series can displace ions of metals lower than themselves on the list If, for example, one placed a piece of tin metal into a solution containing 2+ Cu(NO3)2(aq), the Sn would replace the Cu cation: Sn( s) + Cu( NO3 )2 (aq ) Sn( NO3 )2 (aq ) + Cu( s) Sn(s) + Cu 2+ (aq ) Sn 2+ (aq ) + Cu( s) The second equation is the net ionic form that is often required on the AP exam If a piece of copper metal was placed in a solution of Sn(NO3)2(aq) there would be no reaction, since copper is lower than tin on the activity series This table allows us to also predict that if sodium metal is placed in water, it will displace hydrogen, forming hydrogen gas: 2 Na( s) + 2 H2O( l ) 2 NaOH(aq ) + H 2 ( g ) 2 Na( s) + 2 H 2O( l ) 2 Na + (aq ) + 2 OH (aq ) + H2 ( g ) The Group IA and IIA elements on the activity table will displace hydrogen from water, but not the other metals shown All the metals above hydrogen will react with acidic solutions to produce hydrogen gas: Co( s) + 2 HCl(aq ) CoCl 2 (aq ) + H 2 (g ) Co( s) + 2 H + (aq ) Co 2+ (aq ) + H 2 ( g )
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Reactions and Periodicity 75
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Halogen reactivity decreases as one goes from top to bottom in the periodic table, because of the decreasing electronegativity Therefore, a separate activity series for the halogens can be developed: F2 Cl 2 Br2 I2 The above series indicates that if chlorine gas were dissolved in a KI(aq) solution, the elemental chlorine would displace the iodide ion: Cl 2 (aq ) + 2 KI(aq ) 2 KCl(aq ) + I2 (s) Cl 2 (aq ) + 2 I (aq ) 2 Cl (aq ) + I2 (s)
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Combustion reactions are redox reactions in which the chemical species rapidly combines with oxygen and usually emits heat and light Reactions of this type are extremely important in our society as the sources of heat energy Complete combustion of carbon yields carbon dioxide, and complete combustion of hydrogen yields water The complete combustion of hydrocarbons, organic compounds containing only carbon and hydrogen, yields carbon dioxide and water: 2 C 2H6 ( g ) + 7 O2 ( g ) 4CO2 ( g ) + 6 H 2O( g ) If the compound also contains oxygen, such as in alcohols, ethers, etc, the products are still carbon dioxide and water: 2 CH3OH( l ) + 3 O2 (g ) 2CO2 (g ) + 4 H 2O(g ) If the compound contains sulfur, the complete combustion produces sulfur dioxide, SO2: 2 C 2H6 S(g ) + 9 O2 (g ) 4 CO2 ( g ) + 6 H 2O( g ) + 2 SO2 (g ) If nitrogen is present, it will normally form the very stable nitrogen gas, N2 In all of these reactions, the driving force is the highly reactive oxygen forming a very stable compound(s) This is shown by the exothermic nature of the reaction
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In balancing any of these combustion reactions, it is helpful to balance the oxygen last
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When a salt is dissolved in water, the metal ions, especially transition metal ions, form a complex ion with water molecules and/or other species A complex ion is composed of a metal ion bonded to two or more molecules or ions called ligands These are Lewis 3+ acid base reactions For example, suppose Cr(NO3)3 is dissolved in water The Cr 3+ cation attracts water molecules to form the complex ion Cr(H2O)6 In this complex ion, water acts as the ligand If ammonia is added to this solution, the ammonia can displace the water molecules from the complex: [Cr(H 2O)6 ]3+ ( aq ) + 6 NH3 (aq ) [Cr(NH3 )6 ]3+ (aq ) + 6 H 2O( l )
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