Charging Chemical Reaction in .NET framework

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Charging Chemical Reaction
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The charging process is described at the anode as PbSO4 1 2H20 2e g PbO2 1 4H 1 SO4
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The charging process is described at the cathode as: PbSO4 1 2e g Pb 1 SO4 The charging process (left of Figure 8-1) reverses the electronic flow through the battery and causes the chemical bond between the lead (Pb) and the sulfate (SO4) radicals to be broken, releasing the sulfate radicals back into solution When all the sulfate radicals are again in solution with the electrolyte, the battery is said to be fully charged
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Electrolyte Specific Gravity
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The specific gravity of any liquid is the ratio of the weight of a certain volume of that liquid divided by the weight of an equal volume of water Or the specific gravity of a material can be expressed as its density divided by the density of water, because the density of any material is its mass-to-volume ratio Water has a specific gravity of 1000 Concentrated sulfuric acid has a specific gravity of 1830 183 times as dense as water In a fully charged battery at 80 degrees F, water and sulfuric acid mix in roughly a fourto-one volume ratio (25 percent sulfuric acid) to produce a 1275 specific gravity, and the sulfuric acid represents about 36 percent of the electrolyte by weight While specific gravity is not significant in other battery types, it is important in lead-acid batteries, because the amount of sulfuric acid combining with the plates at any one time is directly proportional to the discharge rate (current 3 time, usually measured in ampere hours), and is therefore a direct indicator of the state-of-charge
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State-of-Charge
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Battery voltage, internal resistance, and amount of sulfuric acid combined with the plates at any one time are all indicators of how much energy is in the battery at any given time Frequently this is given as a percentage of its fully charged value; for example, 75 percent means that 75 percent of the battery s energy is still available and 25 percent has been used Traditionally, the specific gravity of the electrolyte was used as a measurement Today, because voltage can be used to determine a battery s state-of-charge and a hydrometer, the device used to measure specific gravity, can introduce inaccuracy and contaminate a battery s cells, state-of-charge is determined electronically
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Gassing
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As charging nears completion, another phenomenon takes place: hydrogen gas (H2) is given off at the negative cathode plate and oxygen gas (O2) is given off at the positive anode plate This is because any charging current beyond that required to liberate the small amount of sulfate radicals from the plates ionizes the water in the electrolyte and begins the process of electrolysis (separating the water into hydrogen and oxygen gas) While most of the hydrogen and oxygen gas recombines to form water vapor (the main reason that periodic replenishing of the water is needed in this battery type), the presence of flammable and potentially explosive hydrogen gas strongly indicates that charging be conducted in a well-ventilated area, and that you avoid lighting a cigarette
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Equalizing
Over time, the cells of a lead-acid battery begin to show differences in their state-ofcharge Differences can be caused by temperature, materials, construction, electrolyte,
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Batteries
even by electrolyte stratification (the tendency of the heavier sulfuric acid to sink to the lower part of the cell) causing premature aging of the plates in that part The only cure for these differences is to use a controlled overcharge, equalizing the characteristics of the cells by raising the charging voltage even higher after the battery is fully charged, and maintaining it at this level for several hours until the different cells again test identical Obviously, this produces substantial gassing, so the precautions of a wellventilated area and no smoking definitely apply
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