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If the system initially contains 5 mol HC1 for each mole of oxygen, what is the composition of the system at equilibrium Assume ideal gases
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1312 The following reaction reaches equilibrium at 92315 K (650 C) and atmospheric pressure:
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If the system initially is an equimolar mixture of nitrogen and acetylene, what is the composition of the system at equilibrium What would be the effect of doubling the pressure Assume ideal gases
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CHAPTER 13 Chemical-Reaction Equilibria
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1313 The following reaction reaches equilibrium at 62315 K (350 C) 3 bar:
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If the system initially contains 15 mol H2 for each mole of acetaldehyde, what is the composition of the system at equilibrium What would be the effect of reducing the pressure to 1 bar Assume ideal gases
1314 The following reaction reaches equilibrium at 92315 K (650 C) and atmospheric pressure:
If the system initially contains 15 mol Hz for each mole of styrene, what is the composition of the system at equilibrium Assume ideal gases
1315 The gas stream from a sulfur burner is composed of 15-mol-% SO2, 20-mol-% 0 2 , and 65-mol-% N2 This gas stream at 1 bar and 75315 K (480 C) enters a catalytic converter, where the SO2 is further oxidized to SO3Assuming that the reaction reaches equilibrium, how much heat must be removed from the converter to maintain isothermal conditions Base your answer on 1 mol of entering gas 1316 For the cracking reaction,
the equilibrium conversion is negligible at 300 K, but becomes appreciable at temperatures above 500 K For a pressure of 1 bar, determine: (a) The fractional conversion of propane at 625 K (b) The temperature at which the fractional conversion is 85%
1317 Ethylene is produced by the dehydrogenation of ethane If the feed includes 05 mol of steam (an inert diluent) per mole of ethane and if the reaction reaches equilibrium at 1100 K and 1 bar, what is the composition of the product gas on a water-free basis 1318 The production of 1,3-butadienecan be carried out by the dehydrogenation of 1-butene:
Side reactions are suppressed by the introduction of steam If equilibrium is attained at 950 K and 1 bar and if the reactor product contains 10-mol-% 1,3-butadiene,find: (a) The mole fractions of the other species in the product gas (b) The mole fraction of steam required in the feed
1319 The production of 1,3-butadienecan be carried out by the dehydrogenation of n-butane:
C4H10(g)-+ CH2:CHCH:CH2 (g)
+ 2H2(g)
Side reactions are suppressed by the introduction of steam If equilibrium is attained at 925 K and 1 bar and if the reactor product contains 12-mol-% 1,3-butadiene,find: (a) The mole fractions of the other species in the product gas (b) The mole fraction of steam required in the feed
Problems
1320 For the ammonia synthesis reaction,
the equilibrium conversion to ammonia is large at 300 K, but decreases rapidly with increasing T However, reaction rates become appreciable only at higher temperatures For a feed mixture of hydrogen and nitrogen in the stoichiometric proportions, ( a ) What is the equilibrium mole fraction of ammonia at 1 bar and 300 K ( h ) At what temperature does the equilibrium mole fraction of ammonia equal 050 for a pressure of 1 bar (c) At what temperature does the equilibrium mole fraction of ammonia equal 050 for a pressure of 100 bar, assuming the equilibrium mixture is an ideal gas (d) At what temperature does the equilibrium mole fraction of ammonia equal 050 for a pressure of 100 bar, assuming the equilibrium mixture is an ideal solution of gases
1321 For the methanol synthesis reaction,
the equilibrium conversion to methanol is large at 300 K, but decreases rapidly with increasing T However, reaction rates become appreciable only at higher temperatures For a feed mixture of carbon monoxide and hydrogen in the stoichiometric proportions, ( a ) What is the equilibrium mole fraction of methanol at 1 bar and 300 K (b) At what temperature does the equilibrium mole fraction of methanol equal 050 for a pressure of 1 bar (c) At what temperature does the equilibrium mole fraction of methanol equal 050 for a pressure of 100 bar, assuming the equilibrium mixture is an ideal gas (d) At what temperature does the equilibrium mole fraction of methanol equal 050 for a pressure of 100 bar, assuming the equilibrium mixture is an ideal solution of gases
1322 Limestone (CaC03) decomposes upon heating to yield quicklime (CaO) and carbon dioxide At what temperature is the decomposition pressure of limestone l(atm) 1323 Ammonium chloride [NH4Cl(s)]decomposes upon heating to yield a gas mixture of ammonia and hydrochloric acid At what temperature does ammonium chloride exert a decomposition pressure of 15 bar For NH4Cl(s), AH;298= -314 430 J mol-' and AG;298 -202 870 J mol-' = 1324 A chemically reactive system contains the following species in the gas phase: NH3, NO, NOz, 0 2 , and H20 Determine a complete set of independent reactions for this system How many degrees of freedom does the system have 1325 The relative compositions of the pollutants NO and NO2 in air are governed by the reaction,
For air containing 21-mol-% O2 at 29815 K (25 C) and 10133 bar, what is the concentration of NO in parts per million if the total concentration of the two nitrogen oxides is
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