Subject Index in Software

Generating QR Code ISO/IEC18004 in Software Subject Index

Property change of reaction, 126-129, 457462 Property relations, 186-196, 353-360 for constant-composition phase, 186-196 fundamental, 188,353-354,375-377,387 Pseudocritical property, 223 P V T relationships, 58-62, 82-105 equation of state as, 63-66, 82-105 for gas mixture, 521-522 P VT relationships: generalized, 95-105 thermodynamic properties from, 202-207 Quality, 210 Rackett equation, 103 Rankine cycle, 271-275 Raoult's law, 326-333 modified, for low pressures, 335-340 Reaction coordinate, 45 1 4 5 5 RedlicWKister expansion, 416 RedlichIKwong equation of state, 90, 206-207 Soave modification, 93-95 Reduced coordinates, 90 Refrigeration, 294-304 Refrigeration cycle: absorption, 301-303 Carnot, 294-295 cascade, 300-301 vapor-compression, 295-301 Relative volatility, 338 Reservoir, heat, 150, 154, 158 Residual enthalpy, 197-198, 202-204, 205-206,215-221 from equation of state, 202-207 generalized correlation for, 215-222, 650-653 Residual entropy, 197-198, 203,206-207, 215-222 from equation of state, 202-207 generalized correlation for, 215-222, 654-655 Residual Gibbs energy, 196-198,203-207, 369,375-377,522-523 Residual property, 196-207,215-222, 375-377 Residual volume, 196-197, 376 Retrograde condensation, 320 Reversibility, 28-32, 162-165, 169-170 mechanical, 31-32 Reversible chemical reaction, 30-3 1 Riedel equation, for latent heat of vaporization, 125 Rocket engine, 289-290

Saturated liquid and vapor, 60,207, 210 Second law of thermodynamics, 148-149, 162-163, 165,174 statement of, 149, 163 Second virial coefficient: generalized correlation for, 97-98,382-383 from potential function, 608-611 Shaft work, 44 Soave/Redlich/Kwong equation of state, 93-95 Solid/liquid equilibrium (SLE), 557-561 Solidlvapor equilibrium (SVE), 561-565 Solubility diagram, 542-543, 546-547, 564 Sonic velocity in flow, 239, 241-242 Specific heat (see Heat capacity) Spreading pressure, 566-567, 570, 574 SRB, 218,641 Stability criteria, 538-541 Standard Gibbs-energy change: of formation, table of values, 637-638 of reaction, 458 effect of temperature on, 458-459 Standard state, 127 State function, 23-24 Steady-flow process, 4 3 , 4 7 4 8 Steam: Mollier diagram for (see back endpapers) tables, 665-703 Steam power plant, 270-281 Steam turbine, 251-252 Stoichiometric number, 451 Supercritical separation process, 562 Superheat, 210 Surroundings, 12, 19-20 temperature of, 165, 169 System, 12, 19-20 closed, 20 System: heterogeneous, 477 open, 20,42-52 Temperature, 4-564-65, 151-155 absolute zero of, 4, 155 consolute, 542-543 critical, 58-59

effective, for HZ,97 interaction (T,,,), 382 table of values, 632-633 critical-solution,542 normal-boiling-point,125 table of values, 632-633 pseudocritical, 223 reduced, 90 surroundings, 165, 169 Temperaturelcomposition(txy) diagram, 319, 325,332,550,554 Temperaturelentropy (TS) diagram, 221 Temperature scale, 4-5, 65, 155 ideal-gas, 65 International Temperature Scale, 5 y l v i n , 4, 65, 155 t ermodynamic, 151-155 Th modynamic analysis of processes, 590-599 Thermodynamic consistency, 4 1 0 4 1 1 thermodynamic diagrams 210 Thymodynamic properties: of methane, 705 o steam, 665-703 , (See also back endpapers) of tetrafluoroethane, 706 (See also Properties) Thifd law of thermodynamics, 176 Throttling process, 81-82, 245-249, 304305 Tie line, 318,542 Toth equation, 570-574 Triqle point, 58-59 Tro ton's rule, 124 Tur ine, 249-255 Tur ojet, 289 Tw -phase system, 207-209 C apeyron equation for, 207 qpality in, 210 Vaporlliquid equilibrium (VLE): and activity coefficient, 352-353,402-415 infinite-dilution value of, 407 binary-system phase diagrams, 317-318, 330-332,529,535 calculations, block diagrams for, 509-5 13 conditions for stability in, 539-541 correlation by excess Gibbs energy, 404-41 1,414-417 by Margules equation, 407408,414 by NRTL equation, 4 1 6 417 by RedlichIKister expansion, 4 1 5 416 by UNIFAC method, 707-7 13 by van Laar equation, 417 by Wilson equation, 416 dew- and bubblepoint calculations for, 327-333,336-339,343,509-513, 515-516,518,527-529 equations, 326-327,335,507-509,518-534 for high pressure, 518-534 for ideal solution, 326 to moderate pressure, 335 flash calculation, 343-346,5 13-516 and the Gibbs/Duhem equation, 403-404, 410414 for immiscible system, 553-555 K-value for, 339-346, 513-516, 526-528, 531-532 K-values, light hydrocarbons, 341-342 by molecular simulation, 626-627 Vaporlliquid equilibrium (VLE): for partially miscible system, 541-554 for pure species, 207,370,516-518 by Raoult's law, 326-333 reduction of experimental data, 407410 for solutelsolvent systems, 516-518 and thermodynamic consistency, 410415 Vapor/liquid/liquid equilibrium (VLLE), 549-556 Vapor pressure, 58-61,9 1, 124,207-209, 519-521 empirical expressions for, 208-209 Vaporization, 58-61, 124125,207-208 latent heat of, 123-125,207-208 from Clapeyron equation, 124,208 from Riedel equation, 125 from Watson correlation, 125 Velocity, 9-10,4245,239-245 average value in pipes, 4 4 4 5 maximum in pipes, 239

UNIFAC method, 707-713 UNIQUAC equation, 707-708 Units, 2-1 1, 1 4 1 5 cin *o factors, 629-630 Universal gas constant, 65 table of values for, 630 un{teady-state flow process, 4 3 4 7 vanlder Wads equation, 86, 89