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impeller discharge coef cient number of theoretical stages at total re ux actual number of stages in column number of equilibrium stages (theoretical stages) in column order of chemical reaction permeability of membrane pressure of liquid, F / L2 agitator shaft power, E / chemical reactant species vapor pressure of subscripted component, F / L2 number of moles in still-pot (batch distillation) partial pressure of subscripted component, F / L2 stoichiometric coef cient of reactant P impeller discharge rate, L3 / rate of feed of solute-free solvent to raf nate end of extractor, M / chemical reactant species rate of heat transfer, E / stoichiometric coef cient of reactant Q ideal gas constant, E / (T moles) raf nate-layer ow rate, M / re ux ratio speci c reaction rate, or speci c reaction rate of subscripted species (forward reaction), moles / ( L3) speci c reaction rate (reverse reaction), moles / ( L3) average pore radius, L net forward rate of a reversible reaction, moles / ( L3) amount of material distilled in Rayleigh distillation, moles solvent content of extract layer, Msolvent / Mdissolved material empirical constant for lter-cake compressibility average of mutual solubilities of solute-free contacted liquids solvent content of raf nate layer, Msolvent / Mdissolved solids absolute temperature, R or K temperature, C or F overall heat transfer coef cient, E / (L2 T ) dialysis coef cient in subscripted phase, moles / (L2 ) conc total volume upstream of a given point in a plug ow reactor, L3 volume of contactor or reactor, L3 molar vapor rate in column, M / super cial velocity of continuous phase, L3 / (L2 ) super cial velocity of dispersed phase, L3 / (L2 )
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extract-layer ow rate from last stage, M / raf nate-layer ow rate from last stage, M / total volume of feed to ion-exchange process, L3 terminal settling velocity, L / mass of solids retained in lter cake, M bottom product rate, moles / equilibrium composition of raf nate phase, Msolute / Msolute-free phase equilibrium composition of extract phase, Msolution / Msolute-free phase mass fraction solute in raf nate, solvent-free basis moles of subscripted component converted per mole of feed to continuous reactor mole fraction (of subscripted component) in liquid phase mole fraction in liquid phase which would be in equilibrium with actual gas phase at that point in contactor mass fraction of solute in extract, solvent-free basis mole fraction (of subscripted component) in vapor or gas phase mole fraction in vapor phase which would be in equilibrium with actual liquid phase at that point in contactor total column height, L tray spacing, L solvent content of feed, Msolvent / Msolvent-free stream relative volatility reaction order with respect to reactant A speci c cake resistance, L / M empirical constant for wet scrubber ef ciencies empirical constant for lter cake resistance reaction order with respect to reactant B activity coef cient empirical constant for wet scrubber ef ciencies reaction order with respect to reactant C difference or change pressure drop across lter cake, F / L2 time reaction half-life molar latent heat of vaporization, E / moles latent heat of vaporization, E / M viscosity M / (L ) total pressure, F / L2 density, M / L3 reaction order with respect to reactant P
CHAPTER FIFTEEN
density of uid, M / L3 density of particle, M / L3 reaction order with respect to reactant Q interfacial tension, lb mass / hr2 interfacial tension, dynes / cm
Subscripts A B C D d F i L1 L2 lm M m O p P Q w in out 1 2 reactant A reactant B reactant C continuous phase disperse phase distillate product feed stream component i at interface liquid phase 1 liquid phase 2 logarithmic mean molar property molar property initial value in still pot reactant P reactant Q bottom product entering leaving component 1 at position 1 (upstream) or initial time component 2 at position 2 (downstream) or nal time
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