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The municipal application for reverse osmosis is the desalting of brackish water having total dissolved solids between 1000 and 15,000 mg / L Industrially, there are a wide variety of uses The important design parameter is the rate of transport of water across the membrane, called the ux J, which is J where Pg Po C( Pg Po) (1573)
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physical (gage) pressure (feedside-productside) osmotic pressure (feed-product)
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Ion Exchange Ion exchange is a process in which ions, held by electrostatic force to charged functional groups on the surface of a solid, are exchanged for ions of a similar charge in a solution in which the solid is immersed Because the charged functional groups at which exchange occurs are on the surface of the solid, and because the exchanging ions must undergo a phase transfer from liquid phase to residence on a solid phase, ion exchange is a sorption process
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10 Physical-Chemical Processes Physical-chemical treatment (involving coagulation, carbon adsorption, and ltration) is an alternative to biological wastewater treatment methods It replaces microbial stabilization of the dissolved organic matter with a combination of physical treatment processes that do not rely on bacterial action A typical ow diagram for physical-chemical treatment is shown in Fig 1519 11 Disinfection Wastewater treatment processes remove some but not nearly all
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of the pathogens Hence the discharge from biological treatment plants, as well as natural waters contaminated by human sources, can carry diseases caused by bacteria and viruses Thus, disinfection of sewage plant ef uents is widely practiced Chlorination Of all the chemical disinfectants, chlorine is perhaps most commonly used It is reasonably economical, toxic to microorganisms that carry waterborne diseases, tasteless and nonpoisonous to humans at low concentrations, and can be detected in residual amounts some time after application
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FIGURE 1519 Principal operations in physical-chemical treatment
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Chlorine is quite soluble in water 7160 mg / L at 20 C and at atmospheric pressure, forming hypochlorite according to the following equation: Cl2 H2O H O Cl
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(1574)
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When ammonia is present, it reacts to form chloramines, which are slow-acting disinfectants: NH3 NH3 NH3 HOCL NH2Cl 2HOCl NHCl2 3HOCl NCl3 H2O 2H2O 3H2O (1575) (1576) (1577)
Chlorine, present as NH2Cl or NHCl2, is called combined available chlorine When all reducing agents have been satis ed, then free chlorine is detected This is called the breakpoint, which occurs only after the chloramines have been oxidized to N2O and N2 Ozonization A relatively new disinfection method utilizes ozone, a molecule that consists of three atoms of elemental oxygen (O3) In water, these atoms break down rapidly, so they are free to oxidize organic matter and inactivate bacteria and viruses Additionally, ozonization adds oxygen to the system but not dissolved solids Further, ozone will deodorize gases in a few seconds of contact time at low levels of concentration
AIR POLLUTION CONTROL
12 De nitions Air pollution is de ned as the presence in the atmosphere of
one or more contaminants of such quantity and duration as may be injurious to human, plant, or animal life, or property, or which may unreasonably interfere with comfortable enjoyment of life, property, or conduct of business Air pollution results from a two-part phenomenon, a time-concentration relationship Classes of Pollutants Atmospheric pollutants may exist as gases or particulates Frequently, a third category, odors, is recognized Chemically, odors fall into one of the previous categories They are frequently separated because of their objectionable olfactory sensation at concentrations where they are neither toxic nor hazardous Effects SO2 and other acidic pollutants corrode architecture and sculpture (both metals and masonry, especially limestone and marble) Deterioration of historic works has increased signi cantly in the last 50 years Carbonaceous deposits discolor buildings Particulates and condensation nuclei reduce atmospheric visibility, hindering aircraft and ground transportation, block off distant scenic views, and decrease the quantity of solar radiation reaching the earth Pollutants damage vegetation and reduce crop yields
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