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TABLE 154 Types of Equipment Applicable to the Control of Various Classes of Air
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Pollutants Pollutant classi cation Particulate Equipment type Absorption Adsorption Air dispersion (stacks) Condensation Centrifugal (dry) Filtration, bags beds ne bers Gravitational settling Impingement (dry) Incineration Precipitation, electric thermal Wet collection Gas X X X X Odor X X X X Liquid Solid
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CHEMICAL, ENVIRONMENTAL, PETROLEUM AND GAS ENGINEERING
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Generally, the adsorbate is held in liquid phase, even though physical principles would predict that its physical state should be a vapor The adsorbate may be held in the pore structure by direct physical attraction or by the formation of chemical bonds Condensation A number of vapors, especially hydrocarbons with low volatility, can be recovered by condensation A tubular, water-cooled heat exchanger is adequate for many high-molecular-weight organic vapors Where the volatility is greater, a refrigerated condenser following the water-cooled condenser may be necessary In condensing many vapors, where heat transfer is more rapid than mass transfer, fog particles of the condensate (05- to 15- m diameter) are apt to form in the bulk gas stream These particles can result in plume opacity violations as well as a recovery from cooling that is not as great as predicted from vapor pressuretemperature data
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17 Special Gaseous Pollutant Control Methods Two widely released gase-
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ous pollutants are SO2 and NOx Major sources of these pollutants are ue gases from combustion operations Control of these two gases has received wide study, and a number of specialized techniques are available Sulfur Dioxide One control technique is to substitute a low-sulfur or desulfurized fuel Desulfurization has been commercialized for petroleum fuels Several processes have been demonstrated for coal, but it may be several years before they are commercial Nitrogen Oxides Combustion operations are a major source of NOx pollutants O2 and N2 from air react at high temperatures in the ame to produce NO NO reacts more slowly at lower temperatures with O2 to produce NO2 In most furnaces, reaction rates to form NO are too slow to producer equilibrium amounts of NO corresponding to ame temperature, but it is not unusual for the ue gases from oil and coal combustion to contain 1000 to 2000 ppm by volume of NO when using 5 to 10 percent excess air Control of Pollutants by Incineration Incineration is used to destroy combustible vapors such as hydrocarbons (especially unsaturated and aromatic compounds that are photochemically reactive), CO, H2, H2S, and mercaptans
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18 Collection and Removal of Particulates Six basic principles are used
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alone or in combination in particulate collectors: 1 2 3 4 5 6 Gravity settling Flowline interception Inertial deposition Diffusional deposition Electrostatic deposition Thermal precipitation
Table 155 lists these mechanisms and their basic parameters In addition, sonic agglomeration has been considered but has seldom become commercially practical
TABLE 155 Summary of Mechanisms and Parameters in Aerosol Deposition
Deposition mechanism measurable in terms of Basic parameter Ns Db Km sD Vo 18 Db Dv VoDb ut Vo KmQ p b
p 2 p
Deposition mechanism Dp Nsc Nst Nsd 18 Km pDv
2 N s
Origin of force eld
Speci c modifying parameters
System parameters
Flow-line interception* Nsi
Physical gradient*
Inertial deposition
Velocity gradient
Geometry (Db1 / Db), (Db2 / Db), etc
Diffusional deposition Nsd Nsg ,
Concentration gradient
Gravity settling
Elevation gradient
Electrostatic precipitation Nsec Dp Vo
p o p
Electric- eld gradient Attraction Induction Nsei 2 Tb T kt 2kt kt p Km Db Vo Db Vo 1 KmD2 p b2
Nst T
Flow pattern: NRe NMa NKn Surface accommodation
Thermal precipitation
Temperature gradient
( Tb / T ), ( Tp / T ), (NPr) (ktp / kt), (ktb / kt), (chp / ch), (chb / ch)
Not likely to be signi cant contributors * This has also commonly been termed direct interception and in conventional analysis would constitute a physical boundary condition imposed upon particle path induced by action of other forces By itself it re ects deposition that might result with a hypothetical particle having nite size but no mass or elasticity In cases where the body charge distribution is xed and known, b may be replaced with Qbs / o This parameter is an alternative to Ns , Nsl, or Nsd and is useful as a measure of the interactive effect of one of these on the other two It is comparable with the Schmidt number When applied to the inertial deposition mechanism, a convenient alternative is (Km s / 18 ) Nsl / (N 2 NRe) s Source: Perry and Chilton (eds), Chemical Engineers Handbook, 5th ed, McGraw-Hill, New York, 1973, p 20 80
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