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FIGURE 75 Phase and pressure-volume diagrams
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where A and B are constants whose values depend on the substance
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useful in calculations relating to the constant-pressure evaporation of pure substances In such cases the equation may be written as
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4 Properties of Mixtures of Liquid and Vapor The properties of a unit mass
of a mixture of liquid and vapor of quality x (mass fraction) are given by the following expressions:
v v
x v g x h g x u g x s g
(759) (760) (761) (762)
h u s where v g h g u g s g p v g
h u s
v increase of volume during vaporization hg h heat of vaporization (heat required to vaporize unit mass of liquid at constant pressure and temperature) ug u increase of internal energy during vaporization h g sg s increase of entropy during vaporization T work performed during vaporization
Note that the subscripts g and are related to the gas (vapor) and liquid states, respectively Tables 74 through 76 and Figs 714 through 716 are useful for calculating these properties
(continues on page 724)
TABLE 74 Properties of Saturated Water and Water Vapor-Temperature Table
Volume, m3 / kg Enthalpy, kJ / kg h h g hg s s g u ug
Internal energy, kJ / kg
Entropy, kJ / (kg K) sg
P, MPa
T, C
0000611 00008 0001 00012 00014 00016 00018 0002 0003 0004 0006 0008 001 0012 0014 0016 0018 002 003 004 006 008 01 012 014 016 018 02 00 158 293 406 503 589 665 735 1010 1214 1515 1739 1918 2069 2200 2315 2419 2514 2892 3175 3598 3916 4173 4392 4582 4752 4905 5045 23753 23805 23850 23887 23919 23947 23972 23995 24085 24152 24249 24321 24379 24427 24469 24505 24538 24567 24684 24770 24896 24988 25061 25121 25173 25218 25259 25295 00 158 293 406 503 589 665 735 1010 1214 1515 1739 1918 2069 2200 2315 2419 2514 2892 3176 3598 3916 4174 4393 4584 4753 4907 5047 25013 24925 24849 24785 24731 24682 24640 24600 24445 24330 24159 24031 23928 23841 23766 23699 23639 23583 23361 23191 22937 22741 22581 22442 22320 22212 22111 22019 25013 25083 25142 25191 25234 25271 25305 25335 25455 25544 25674 25770 25846 25910 25966 26014 26058 26097 26253 26367 26535 26657 26755 26835 26904 26965 27018 27066 00000 00575 01059 01460 01802 02101 02367 02606 03544 04225 05208 05924 06491 06961 07365 07719 08034 08319 09439 10260 11455 12331 13029 13611 14112 14553 14948 15305
001 38 70 97 120 140 158 175 241 290 362 415 458 494 526 553 578 601 691 759 859 935 996 1048 1093 1133 1169 1202
0001000 0001000 0001000 0001000 0001001 0001001 0001001 0001001 0001003 0001004 0001006 0001008 0001010 0001012 0001013 0001015 0001016 0001017 0001022 0001026 0001033 0001039 0001043 0001047 0001051 0001054 0001058 0001061
2061 1597 1292 1087 9392 8276 7403 6700 4567 3480 2374 1810 1467 1236 1069 9433 8445 7649 5229 3993 2732 2087 1694 1428 1237 1091 09775 08857
91571 90007 88706 87639 86736 85952 85259 84639 82240 80529 78104 76371 75019 73910 72968 72149 71425 70774 68256 66449 63873 62023 60573 59378 58360 57472 56683 55975
91571 90582 89765 89099 88538 88053 87626 87245 85784 84754 83312 82295 81510 80871 80333 79868 79459 79093 77695 76709 75328 74354 73602 72989 72472 72025 71631 71280
03 04 06 08 1 12 14 16 18 2 3 4 6 8 9 10 12 14 16 18 20 22088 5611 6043 6699 7202 7617 7973 8287 8569 8827 9064 10048 10823 12054 13056 13505 13930 14729 15486 16227 16989 17856 20296 16722 17770 19316 20466 21391 22170 22847 23446 23986 24478 26462 27970 30273 32075 32865 33603 34970 36240 37468 38722 40146 44305 53205 51197 48293 46170 44482 43072 41854 40780 39816 38939 35416 32739 28627 25365 23916 22546 19963 17486 14996 12332 09135 00000 25436 25536 25674 25768 25836 25888 25928 25960 25984 26003 26041 26023 25897 25698 25578 25444 25137 24768 24318 23744 22932 20296 5615 6047 6706 7211 7628 7986 8303 8588 8848 9088 10084 10873 12133 13166 13633 14076 14913 15711 16500 17320 18263 20993 21638 21338 20862 20480 20153 19862 19597 19352 19123 18907 17957 17141 15710 14414 13788 13171 11936 10665 9307 7772 5837 00 27253 27385 27568 27691 27781 27848 27900 27940 27971 27995 28041 28014 27843 27580 27421 27247 26849 26376 25807 25092 24100 20993
1335 1436 1589 1704 1799 1880 1951 2014 2072 2124 2339 2504 2756 2951 3034 3111 3248 3368 3474 3571 3658 374136
0001073 0001084 0001101 0001115 0001127 0001139 0001149 0001159 0001168 0001177 0001216 0001252 0001319 0001384 0001418 0001452 0001527 0001611 0001711 0001840 0002036 0003155
06058 04625 03157 02404 01944 01633 01408 01238 01104 009963 006668 004978 003244 002352 002048 001803 001426 001149 0009307 0007491 0005836 0003155
69927 68967 67609 66636 65873 65242 64701 64226 63802 63417 61878 60709 58900 57440 56781 56149 54933 53726 52464 51054 49281 44305
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