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Solar Hydrogen Partnership
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Figure 17-1 Fuel cell technology focus.
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Figure 17-2 Fuel cell construction.
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generally made from stainless steel, as it does not react with the chemicals present. The stainless steel is perforated to allow the gas to penetrate. The next assembly of carbon cloth/paper and Nafion membrane is termed an MEA, or membrane electrode assembly. This is the bit that makes the reaction take place that produces the energy. Next we have a carbon cloth or paper. The gas can permeate this quite easily, one side the side
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that interfaces with the Nafion membrane (more on that later) contains a quantity of platinum which acts as a catalyst for the reaction that will take place next. Now the Nafion membrane but first a little explanation! For those of you who were wondering, Nafion is a sulfonated tetrafluoroethylene copolymer. Are you any the wiser Well Nafion is a special kind of
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Project 45: Generating Hydrogen Using Solar Energy
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plastic developed by DuPont in the 1960s. It s very special properties are essential to the operation of the PEM fuel cell. Essentially, what happens is that electrons cannot pass through the Nafion membrane but protons can. The platinum on the carbon cloth facilitates the separation of the electrons from the protons in the hydrogen atom. The protons are allowed to pass through the membrane; however, the electrons can t get through. Instead, they take the next easiest route. The carbon cloth acts as a conductor. It allows the electrons to find a path to the stainless steel mesh. The mesh forms the electrode, which is connected to the circuit that the fuel cell powers. The circuit presents the route of least resistance,
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so the electrons make their way through the circuit. As they do this they perform some useful work which we can harness. On the other side of the Nafion membrane is a mirror image assembly, with another set of carbon cloth, stainless steel electrode, and end plate. At the other side, the electrons are reunited with the protons that have passed through the membrane, and the all-essential oxygen. The protons, electrons, and oxygen combine to form H2O better known as water. We will look at this process in more detail later, but first let s get on with generating some hydrogen!
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In this project, we are going to look at the potential for a solar-hydrogen economy. We are going to start with a simple experiment to generate hydrogen using a solar cell to provide the electricity to electrolyze water.
PEM reversible fuel cell (Fuel Cell Store part no. 632000) Photovoltaic solar cell (Fuel Cell Store part no. 621500) Gas storage tank (2 ) (Fuel Cell Store part no. 560207) Rubber tubing Distilled water (not just purified!)
Familiarizing ourselves with the stuff!
If you have bought the items above, the chances are that you have got a lot of cool stuff, but are none too sure what to do with it. Don t panic! We are going to look at what the stuff does, and how it all goes together in this section. First is our fuel cell, shown in Figures 17-3 to 17-5. First of all, you should note two terminals on the top one red, one black. It should be apparent that these are the supply terminals for the fuel cell. Then, if we look on either side of the fuel cell, we see that there are intake pipes for gas. There should be two, these are diagonally offset in the fuel cell specified above.
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Fuel cell tech spec
PEM reversible fuel cell 2 2 1/2 in. (5 5 12.5 cm) 2.4 oz. (68 grams) 0.95 volts open circuit 350 MA
Project 45: Generating Hydrogen Using Solar Energy
Figure 17-5 PEM fuel cell with rubber hoses.
Figure 17-3 PEM fuel cell with caps.
Figure 17-4 PEM fuel cell without caps. Figure 17-6 40 ml gas tank filled with water.
You will see that one side of the fuel cell has a label H2, this is the hydrogen side; the other side has the label O2, this is where the oxygen goes. The fuel cell comes supplied with some little caps as shown in Figure 17-3. These can be used to prevent water from escaping. These caps can be removed if desired, and two little plastic tubes are exposed for connection to the gas tanks (more about this later). Small lengths of rubber
tube are shown attached to the fuel cell in Figure 17-5. Next we have the gas tanks shown in Figures 17-6 and 17-7. We can see how in the first instance we fill the gas tanks with water this is illustrated in Figure 17-6. Then, as shown in Figure 17-7, as our fuel cells produce gas, the gas displaces the water
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