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WASTE MANAGEMENT GOALS AND OPPORTUNITIES
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nal consumer employ more administrative and marketing personnel. Industries that market their products mostly to industrial customers generally employ a greater proportion of precision production workers and a lower proportion of unskilled labor. The chemical manufacturing subsector is based on the transformation of organic and inorganic raw materials by a chemical process and the formulation of products. This subsector distinguishes the production of basic chemicals that comprise the rst industry group from the production of intermediate and end-products produced by further processing of basic chemicals that make up the remaining industry groups. This subsector does not include all industries transforming raw materials by a chemical process. It is common for some chemical processing to occur during mining operations. These bene ciating operations, such as copper concentrating, are classi ed in sector 21, mining. Furthermore, the re ning of crude petroleum is included in subsector 324, petroleum and coal products manufacturing. In addition, the manufacturing of aluminum oxide is included in subsector 331, primary metal manufacturing; and beverage distilleries are classi ed in subsector 312, beverage and tobacco product manufacturing. As in the case of these two activities, the grouping of industries into subsectors may take into account the association of the activities performed with other activities in the subsector. The petroleum and coal products manufacturing subsector is based on the transformation of crude petroleum and coal into usable products. The dominant process is petroleum re ning that involves the separation of crude petroleum into component products through such techniques as cracking and distillation. In addition, this subsector includes establishments that primarily further process re ned petroleum and coal products and produce products, such as asphalt coatings and petroleum lubricating oils. However, establishments that manufacture petrochemicals from re ned petroleum are classi ed in industry 32511, petrochemical manufacturing.
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30.2 Waste Management Goals and Opportunities
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The majority of solid waste generated by this sector is solidi ed sludge and mixed of ce paper. Table 30.1 displays the composition breakdown based on survey results. As shown in the table, the recycling rate for this sector is approximately 28 percent. As derived from the solid waste evaluation model discussed in Chap. 12, the equation that estimates the annual waste generation per year per employee for this sector can be calculated from the following: Tons of solid waste generated per year = 7.14 number of employees 3.49 solid waste disposal cost per ton 140.4 if the company is ISO 140001 certi ed + 371.1
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CHEMICAL AND PETROLEUM PROCESSING APPLICATIONS
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TABLE 30.1 CHEMICAL AND RUBBER-PROCESSING INDUSTRY SOLID WASTE COMPOSITION (SURVEY RESULTS) MATERIAL COMPOSITION (%) RECYCLING (%)
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Plastics HDPE PP PET PVC Paper Mixed of ce paper Newspaper OCC (cardboard) Wood Metals Food waste Glass Yard waste Other Overall recycling level
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7.4 1.6 1.2 0.9 0.9
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3.2 3.2 2.8 3.2 2.8
20 6.2 17 4.9 2 0.6 12 3.7 9 2.8 9 2.8 6 1.9 2 0.6 2 0.6 16 N/A
20 8.0 19 7.6 14 5.6 46 17.1 91 18.4 89 4.2 0 0.0 5 2.0 0 0.0 0 0.0 27.7
30.3 Constraints and Considerations
The critical constraints in the chemical and rubber sector relate to the hazardous materials and by-products that are used and generated during operations. These hazardous materials can contaminate potentially recyclable materials, such as chemicals on plastic tubs or wood pallets. Once contaminated, these materials must also be treated as hazardous. The majority of the waste generated by this sector is plastic waste used to house input materials and paper streams.
30.4 Potential Technologies and Strategies
To combat the contaminate issue; several strategies are available ranging from process changes to equipment purchases. The rst low-cost strategy involves separating waste to avoid contamination. Such strategies to prevent contamination include
CASE STUDY
Clearly label the recycling bins and waste containers on site. Post lists of recyclable and nonrecyclable materials. Conduct regular site visits to verify that bins are not contaminated.
If contamination cannot be avoided, washing machines can be purchased to remove contaminates, or a recycling vendor can be hired who has the means to clean the recyclable materials. The downside of utilizing a vendor to wash parts is an additional cost. A cost comparison and break-even analysis should be performed to determine if hiring a vendor or completing the work in-house is more cost-effective.
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