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Silver-oxide cells can be stacked to make batteries. Several of these miniature cells, one on top of the other, might provide 6 V or 9 V for a transistor radio or other light-duty electronic device. The resulting battery is about the size of an AAA cylindrical cell.
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Mercury cells, also called mercuric oxide cells, have advantages similar to silver-oxide cells. They are manufactured in the same general form. The main difference, often not of significance, is a somewhat lower voltage per cell: 1.35 V. If six of these cells are stacked
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Nickel-cadmium cells and batteries 125 to make a battery, the resulting voltage will be about 8.1 V rather than 9 V. One additional cell can be added to the stack, yielding about 9.45 V. There has been some decrease in the popularity of mercury cells and batteries in recent years. This is because of the fact that mercury is highly toxic. When mercury cells and batteries are dead, they must be discarded. Eventually the mercury, a chemical element, leaks into the soil and ground water. Mercury pollution has become a significant concern in places that might really surprise you.
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Lithium cells have become popular since the early eighties. There are several variations in the chemical makeup of these cells; they all contain lithium, a light, highly reactive metal. Lithium cells can be made to supply 1.5 V to 3.5 V, depending on the particular chemistry used. These cells, like their silver-oxide cousins, can be stacked to make batteries. The first applications of lithium batteries was in memory backup for electronic microcomputers. Lithium cells and batteries have superior shelf life, and they can last for years in very-low-current applications such as memory backup or the powering of a digital liquid-crystal-display (LCD) watch or clock. These cells also provide energy capacity per unit volume that is vastly greater than other types of electrochemical cells. Lithium cells and batteries are used in low-power devices that must operate for a long time without power-source replacement. Heart pacemakers and security systems are two examples of such applications.
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You ve already seen the basic configuration for a lead-acid cell. This has a solution of sulfuric acid, along with a lead electrode (negative) and a lead-dioxide electrode (positive). These batteries are rechargeable. Automotive batteries are made from sets of lead-acid cells having a free-flowing liquid acid. You cannot tip such a battery on its side, or turn it upside-down, without running the risk of having some of the acid electrolyte get out. Lead-acid batteries are also available in a construction that uses a semisolid electrolyte. These batteries are popular in consumer electronic devices that require a moderate amount of current. Notebook or laptop computers, and portable video-cassette recorders (VCRs), are the best examples. A large lead-acid battery, such as the kind in your car, can store several tens of ampere-hours. The smaller ones, like those in notebook computers, have less capacity but more versatility. Their overwhelming advantage is their ability to be used many times at reasonable cost.
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You ve probably seen, or at least heard of, NICAD cells and batteries. They have become quite common in consumer devices such as those little radios and cassette players you can wear while doing aerobics or just sitting around. (These entertainment units are not too safe for walking or jogging in traffic. And never wear them while riding a bicycle.) You can
126 Cells and batteries buy two sets of cells and switch them every couple of hours of use, charging one set while using the other. Plug-in charger units cost only a few dollars.
Types of NICAD cells
Nickel-cadmium cells are made in several types. Cylindrical cells are the standard cells; they look like dry cells. Button cells are those little things that are used in cameras, watches, memory backup applications, and other places where miniaturization is important. Flooded cells are used in heavy-duty applications and can have a charge capacity of as much as 1,000 Ah. Spacecraft cells are made in packages that can withstand the vacuum and temperature changes of a spaceborne environment.
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