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D E T O X I F I C AT I O N : T H E K E Y T O W E L L N E S S
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Researchers at Ohio University have found that certain free radicals, also known as oxidants, play a key role in repairing blood vessels damaged by the buildup of cholesterol. Dr. Goldschmidt, director of the university s Heart and Lung Institute, told the Journal of Circulation Research that oxidants often have a highly positive effect on the process. In addition, protective immune cells called macrophages use free radicals to kill bacteria and viruses. Only in excess are free radicals dangerous. It is now possible to determine the level of free radical damage in an individual by taking a blood or urine sample. This will be discussed further in 9.
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In the enzymatic processes, a group of important antioxidant enzymes work together systematically to destroy various free radicals and other reactive oxygen species. All of us inherit these enzymes to some degree. Those with high levels won t have much trouble with free radicals, but those with low levels need to take special care. Most of us fall somewhere in between. Here again, I must risk becoming overly technical in order to explain how these processes work. The antioxidant enzymes important to the enzymatic processes include several superoxide dismutases (SODs), catalase, glutathione peroxidase, glutathione reductase, thioredoxin reductase, and ascorbic acid reductase. How they are employed depends on the task at hand. Take, for example, superoxide, a highly reactive oxygen molecule. The formation of superoxide is a normal physiological process, but excessive amounts can lead to damage and must be detoxified. There are three different SODs that enzymatically convert the dangerous superoxide molecule to hydrogen peroxide, and then the antioxidant enzyme catalase finishes the job by converting hydrogen peroxide to harmless water and normal oxygen. These SODs need manganese, copper, and/or zinc for their important antioxidant function. Another family of antioxidant enzymes, ones that contain the important mineral selenium, is called glutathione peroxidases. These enzymes are capable of neutralizing other types of peroxides, such as lipid peroxides, which can give rise to free radicals and alter important lipids in the body s cellular and nuclear membranes leading to a chain reaction called lipid peroxidation. This process is definitely not good for cells and can be a factor in many degenerative diseases.
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For antioxidants to be effective in destroying all types of free radicals, they must be in what we call a reduced state. The antioxidant enzymes glutathione reductase and thioredoxin reductase (another seleniumcontaining enzyme) play an important role in this. Finally, ascorbic acid reductase keeps ascorbic acid (vitamin C), an important dietary antioxidant from fruits and vegetables, in a reduced state so that it can effectively neutralize certain free radicals and in turn help to keep vitamin E, another antioxidant, in a reduced state as well. The cells of our body produce many chemicals with antioxidizing activity against free radicals. Important examples include glutathione, which is probably the best known, as well as coenzyme Q10 (CoQ10), alpha lipoic acid, L-methionine, L-glutamine, taurine, bilirubin, cysteine, and uric acid. These antioxidants help protect important DNA, proteins, and lipids from free radical damage. Fruits, vegetables, whole grains, and legumes contain many dietary antioxidants to help fight against free radicals including vitamin E, vitamin C (ascorbic acid), and several carotenoids including -carotene, lutein, and lycopene. These foods also contain many different phytochemicals with antioxidant properties including flavonoids, isoflavones, polyphenols, sulfur-containing compounds, and terpenoids. In addition to the direct effect that antioxidant activity has on keeping free radicals in check, it also gives support to xenobiotic Phase I and II enzymes further improving the overall detoxification process. The xenobiotic and the antioxidant detoxification systems work together to decrease the burdens imposed by toxins and free radicals, allowing individuals to live longer and healthier lives.
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