Sources of Free Radicals Handled by the Antioxidant Detoxification System in .NET framework

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Sources of Free Radicals Handled by the Antioxidant Detoxification System
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Detoxification of Heavy Metals
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Detoxification of heavy metals such as lead, mercury, cadmium, and nickel is a complex function. The body processes metals through a particular metabolic pathway, depending on whether they appear as organic or inorganic compounds or as the elemental metals. Characteristically, heavy metals accumulate slowly in the body and have half-lives that may span many years. This causes a disruption of homeostatis or normal cellular and organ function, which can lead to a disease state. Heavy metals can alter normal mineral balance, suppress the immune system, and do damage to the brain, heart, kidneys, and liver. Heavy metals are more absorbable on an empty stomach, so it is always advisable to eat regularly and avoid skipping meals. Not surprisingly, fruits and vegetables are at the top of my list of foods I recommend be eaten with great frequency because we know that many phytochemicals contained in them, including polyphenols and silymarin, are able to bind (chelate) heavy metals and help prevent absorption. Even if heavy metals are absorbed, sulfur- and sulfhydryl-containing amino acids, such as L-methionine and cysteine, are very effective components in their detoxification. Glutathione, a sulfur-containing molecule, is one of the key agents in the body for the detoxification of heavy metals. Methylsulfonyl-methane (MSM), which occurs naturally in the body, in addition to being an effective free radical scavenger, is an excellent source of sulfur for this purpose.
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MSM and N-acetylcysteine (NAC) are both very effective antioxidants and detoxifiers of heavy metals.
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Methylation: At the Forefront of Nutrition Research
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Methylation is a biochemical process that is crucial for life. It is the initiator of many protective activities, such as transcribing genes, creating or converting critical compounds, and detoxifying harmful chemicals, including homocysteine. The liver, the major detoxification organ, depends on methylation to perform many enzymatic reactions required to detoxify drugs and foreign chemicals. Recent breakthroughs in the study of this process have propelled it to the forefront of scientific interest.
THE DETOX REVOLUTION
The primary methylating substance, s-adenosylmethionine (SAMe) is formed when methionine, an amino acid, reacts with adenosine triphosphate (ATP), an energy molecule. Although not an antioxidant, SAMe reverses DNA damage by free radicals. Levels of SAMe have been shown to decrease with age. Methylation deficiencies can bring on cancer and other chronic diseases such as heart disease, depression, and accelerated aging. Elevated homocysteine levels can be a sign of a methylation deficiency throughout the body. High levels of homocysteine can cause lipid peroxidation and sticky platelets and can promote the oxidation of low-density lipoprotein (LDL) cholesterol. In general when cholesterol is elevated, so is homocysteine; both situations are known indicators for heart disease and stroke. To maintain a low level of homocysteine, it has to be methylated by SAMe and converted back to methionine or cysteine, which is further converted to glutathione. Natural detoxification of homocysteine can only occur when enough B vitamins are present. The conversion to methionine requires sufficient folate and vitamin B12; the conversion to glutathione requires sufficient vitamin B6. These vitamins plus trimethylglycine (TMG) are effective in lowering homocysteine. Most Americans eat plenty of meat so they get large amounts of methionine. Unfortunately, however, the majority of Americans do not eat enough fresh vegetables and whole grains to get sufficient B vitamins. B vitamins are essential in keeping elevated homocysteine from becoming a health problem. With new breakthroughs in the study of methylation, we now have an answer for why free radicals damage DNA and in turn cause cancer, a question that has eluded scientists for decades. Researchers at Northwestern University found that when a small area of DNA is oxidized, the result is that methylation is altered. As soon as this occurs, protective genetic function is eliminated and cancer genes are free to activate. Scientists now realize that free radical damage occurs through abnormal methylation and that normal methylation keeps cancer genes at bay.
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